gtcrustГеодинамика и тектонофизикаGeodynamics & Tectonophysics2078-502XInstitute of the Earth's crust of the Russian Academy of Sciences, Siberian Branch10.5800/GT-2022-13-2s-0605gtcrust-1491Research ArticleПАЛЕОГЕОДИНАМИКАPALEOGEODYNAMICSЛОКАЛЬНЫЙ АНАЛИЗ МИКРОЭЛЕМЕНТНОГО СОСТАВА СИЛИКАТНЫХ МИНЕРАЛОВ НА МАСС-СПЕКТРОМЕТРЕ NEXION 300S С ЛА ПРИСТАВКОЙ NWR 213: МЕТОДИЧЕСКИЕ АСПЕКТЫLA-ICP-MS ANALYSIS OF TRACE ELEMENTS IN SILICATE MINERALS ON ICP-MS NEXION 300S MASS SPECTROMETER WITH NWR 213 ATTACHMENT FOR LASER ABLATION: METHODOLOGICAL ASPECTSЧервяковскаяМ. В.ChervyakovskayaM. V.

620016, Екатеринбург, ул. Академика Вонсовского, 15

15 Academician Vonsovsky St, Ekaterinburg 620016

ЧервяковскийВ. С.ChervyakovskiyV. S.

620016, Екатеринбург, ул. Академика Вонсовского, 15

15 Academician Vonsovsky St, Ekaterinburg 620016

ВотяковС. Л.VotyakovS. L.

620016, Екатеринбург, ул. Академика Вонсовского, 15

15 Academician Vonsovsky St, Ekaterinburg 620016

Институт геологии и геохимии им. А.Н. Заварицкого УрО РАНРоссияZavaritsky Institute of Geology and Geochemistry, Ural Branch of the Russian Academy of SciencesRussian Federation202214062022132605605Copyright © Червяковская М.В., Червяковский В.С., Вотяков С.Л., 20222022Червяковская М.В., Червяковский В.С., Вотяков С.Л.Chervyakovskaya M.V., Chervyakovskiy V.S., Votyakov S.L.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.gt-crust.ru/jour/article/view/1491

Масс-спектрометрия с индуктивно связанной плазмой (ИСП-МС) и лазерной абляцией (ЛА) широко применяется для изучения микроэлементного состава минералов, в том числе силикатных. Тем не менее в настоящее время методические работы в этой области, цель которых – повышение чувствительности и локальности, снижение погрешности определения, остаются актуальными. В статье описаны методические подходы к изучению микроэлементного состава ряда силикатных минералов, реализованные на квадрупольном ИСП-МС NexION 300S с ЛА приставкой NWR 213, полученные на стандартных синтетических стеклах NIST SRM 612 и 610, а также на ряде межлабораторных образцов сравнения циркона Mud Tank, GJ–1, 91500, Plesovice, Temora-2 и внутрилабораторных образцов сравнения клинопироксена 1636 и 1780 из клинопироксенита Нижнетагильского массива (Урал). Представлены метрологические характеристики методики анализа (правильность определения элементов от Li до U) и вариации чувствительности по разным элементам, полученные при диаметре кратера 13, 20, 25, 50 и 100 мкм; проанализирован дрейф чувствительности МС за время аналитической сессии в течение 8 ч, проведена сравнительная характеристика полученных и литературных данных; получено удовлетворительное согласие результатов. Достигнутые погрешности анализа позволяют использовать методики для проведения исследований при решении различных геохимических проблем.

Inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation (LA) are widely used to study the trace element composition of minerals, including silicates; nevertheless, methodological activities in this area aimed at increasing the sensitivity and locality and reducing composition error, remain relevant. The paper describes methodological approaches for studying the trace element composition of a number of silicate minerals using NexION 300S quadrupole ICP-MS with an NWR 213 LA attachment, obtained on standard synthetic glasses NIST SRM 612 and 610, as well as a number of interlaboratory zircon standards Mud Tank, GJ-1, 91500, Plesovice, Temora-2 and clinopyroxene samples 1636 and 1780 from clinopyroxenite of the Nizhniy Tagil massif (Urals). Presented here are the metrological characteristics of the analysis technique (the accuracy in the determination of elements from Li to U) and variations in sensitivity for different elements, obtained with a crater diameter of 13, 20, 25, 50 and 100 microns. The MS sensitivity drift analysis has been performed through an 8-hour analytical session; a comparison has been made between the results obtained and the literature data; a satisfactory agreement of the results has been observed. The analytical errors allow the use of methods for conducting research in solving various geochemical problems.

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The authors declare that there are no conflicts of interest present.