gtcrustГеодинамика и тектонофизикаGeodynamics & Tectonophysics2078-502XInstitute of the Earth's crust of the Russian Academy of Sciences, Siberian Branch10.5800/GT-2021-12-2-0528gtcrust-1215Research ArticleПАЛЕОГЕОДИНАМИКАPALEOGEODYNAMICSZr-Th-U МИНЕРАЛЫ В ВЫСОКОМАГНЕЗИАЛЬНОМ ДИОРИТЕ ЧЕЛЯБИНСКОГО МАССИВА (ЮЖНЫЙ УРАЛ) – ИНДИКАТОРЫ МАНТИЙНО-КОРОВОГО ВЗАИМОДЕЙСТВИЯZr-Th-U MINERALS IN HIGH-MG DIORITE OF THE CHELYABINSK MASSIF (SOUTH URALS) – EVIDENCE FOR CRUST–MANTLE INTERACTIONОсиповаТ. А.OsipovaT. A.

620016 Екатеринбург, ул. Академика Вонсовского, 15

15 Academician Vonsovsky St, Ekaterinburg 620016

osipova@igg.uran.ruКаллистовГ. А.KallistovG. A.

620016 Екатеринбург, ул. Академика Вонсовского, 15

15 Academician Vonsovsky St, Ekaterinburg 620016

ЗамятинД. А.ZamyatinD. A.

620016 Екатеринбург, ул. Академика Вонсовского, 15

15 Academician Vonsovsky St, Ekaterinburg 620016

БулатовВ. А.BulatovV. A.

620016 Екатеринбург, ул. Академика Вонсовского, 15

15 Academician Vonsovsky St, Ekaterinburg 620016

Институт геологии и геохимии им. А.Н. Заварицкого УрО РАНРоссияZavaritsky Institute of Geology and Geochemistry, Ural Branch of the Russian Academy of SciencesRussian Federation202123062021122350364Copyright © Осипова Т.А., Каллистов Г.А., Замятин Д.А., Булатов В.А., 20212021Осипова Т.А., Каллистов Г.А., Замятин Д.А., Булатов В.А.Osipova T.A., Kallistov G.A., Zamyatin D.A., Bulatov V.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.gt-crust.ru/jour/article/view/1215

В высокомагнезиальном диорите, слагающем синплутоническую дайку позднедевонско-раннекаменноугольного возраста в гранодиоритах Челябинского гранитоидного массива на Южном Урале, выявлена ассоциация Zr-Th-U минералов, представленная бадделеитом, ураноторианитом и цирконом. Минералы микронного размера исследовались методом электронной микроскопии и катодолюминесценции, а химический состав определялся методом электронно-зондового микроанализа (ЭЗМА), который был оптимизирован для измерения состава минералов с высокой локальностью. Бадделеит присутствует в виде включений субидиоморфных кристаллов в амфиболе и в межзерновом пространстве. Заключенный в амфиболе бадделеит сохраняет свой состав и не подвергается коррозии или замещению. В межзерновом пространстве в результате реакции с кремнекислым расплавом бадделеит замещается полизернистым цирконом с одновременным образованием ураноторианита, что позволяет предположить реститовую природу бадделеита. Главная особенность его состава – экстремально высокие концентрации ThO2 (до 0.3 мас. %) и UO2 (до 1 мас. %) – может быть связана с метасоматозом мантийного перидотита с участием корового или карбонатитового расплава/флюида.

Zr-Th-U minerals, namely baddeleyite, zircon and U-Th-oxide, were found in high-Mg diorite from the Late Devonian – Early Carboniferous synplutonic dyke in granodiorites of the Chelyabinsk massif, South Urals. Micron-sized minerals were investigated by electron microscopy and cathodoluminescence spectroscopy. Their chemical compositions were determined by electron probe microanalysis that was optimized to ensure more precise measurements of the composition of minerals. Baddeleyite grains are found as inclusions in amphibole crystals and reside in intergranular areas. The former retain their composition and show no traces of corrosion or substitution. In the intergranular areas, baddeleyite grains were replaced by polycrystalline zircon due to the reaction with an acid melt, and the U-Th-oxide precipitated inside baddeleyite simultaneously, which suggests the restite origin of baddeleyite. The main features of the baddeleyite composition are extremely high concentrations of ThO2 and UO2 (to 0.03 wt. % and 1.0 wt. %, respectively), which may be due to the metasomatic interaction between the mantle peridotite and the crustal or carbonatite fluid or melt.

высокомагнезиальный диоритбадделеитураноторианитцирконпетрогенезисмантийно-коровое взаимодействиеЮжный Уралкатодолюминесценцияэлектронно-зондовый микроанализhigh-Mg dioritebaddeleyiteuranotorianitezirconpetrogenesiscrust–mantle interactionSouth Uralscathodoluminescenceelectron probe microanalysisРабота выполнена в рамках государственного задания ИГГ УрО РАН (№ гос. рег. тем АААА-А18-118052590029-6 и АААА-А19-119071090011-6).The study was carried out under the state assignment of the Institute of Geology and Geochemistry UB RAS (project АААА-А18-118052590029-6 and АААА-А19-119071090011-6).ReferencesAbersteiner A., Kamenetsky V.S., Goemann K., Giuliani A., Howarth G.H., Castillo-Oliver M., Thompson J., Kamenetsky M., Cherry A., 2019. Composition and Emplacement of the Benfontein Kimberlite Sill Complex (Kimberley, South Africa): Textural, Petrographic and Melt Inclusion Constraints. Lithos 324–325, 297–314. https://doi.org/10.1016/j.lithos.2018.11.017.Abersteiner A., Kamenetsky V.S., Goemann K., Giuliani A., Howarth G.H., Castillo-Oliver M., Thompson J., Kamenetsky M., Cherry A., 2019. Composition and Emplacement of the Benfontein Kimberlite Sill Complex (Kimberley, South Africa): Textural, Petrographic and Melt Inclusion Constraints. Lithos 324–325, 297–314. https://doi.org/10.1016/j.lithos.2018.11.017.Amelin Y., Li C., Naldrett A.J., 1999. Geochronology of the Voisey’s Bay Intrusion, Labrador, Canada, by Precise U–Pb Dating of Coexisting Baddeleyite, Zircon, and Apatite. Lithos 47 (1–2), 33–51. https://doi.org/10.1016/s0024-4937(99)00006-7.Amelin Y., Li C., Naldrett A.J., 1999. Geochronology of the Voisey’s Bay Intrusion, Labrador, Canada, by Precise U–Pb Dating of Coexisting Baddeleyite, Zircon, and Apatite. Lithos 47 (1–2), 33–51. https://doi.org/10.1016/s0024-4937(99)00006-7.Anfilogov V.N., Krasnobaev A.A., Ryzhkov V.M., 2018. Ancient Age of Zircons and Problems of Dunits Genesis from Gabbro-Hyperbasez Complexes of Folded Areas and Central Type Platform Massives. Lithosphere 18 (5), 706–717 (in Russian) [Анфилогов В.Н., Краснобаев А.А., Рыжков В.М. Древний возраст цирконов и проблемы генезиса дунитов габбро-гипербазитовых комплексов складчатых областей и платформенных массивов центрального типа // Литосфера. 2018. Т. 18. № 5. С. 706–717]. https://doi.org/10.24930/1681-9004-2018-18-5-706-717.Anfilogov V.N., Krasnobaev A.A., Ryzhkov V.M., 2018. Ancient Age of Zircons and Problems of Dunits Genesis from Gabbro-Hyperbasez Complexes of Folded Areas and Central Type Platform Massives. Lithosphere 18 (5), 706–717 (in Russian) [Анфилогов В.Н., Краснобаев А.А., Рыжков В.М. Древний возраст цирконов и проблемы генезиса дунитов габбро-гипербазитовых комплексов складчатых областей и платформенных массивов центрального типа // Литосфера. 2018. Т. 18. № 5. С. 706–717]. https://doi.org/10.24930/1681-9004-2018-18-5-706-717.Bao Z., Shi Y., Anderson J.L., Kennedy A., Ke Z., Gu X., Wang P., Che X., Kang Y., Sun H., Wang C., 2020. Petrography and Chronology of Lunar Meteorite Northwest Africa 6950. Science China Information Sciences 63, 140902. https://doi.org/10.1007/s11432-019-2809-3.Bao Z., Shi Y., Anderson J.L., Kennedy A., Ke Z., Gu X., Wang P., Che X., Kang Y., Sun H., Wang C., 2020. Petrography and Chronology of Lunar Meteorite Northwest Africa 6950. Science China Information Sciences 63, 140902. https://doi.org/10.1007/s11432-019-2809-3.Bhushan S.K., Somani O.P., 2019. Rare Earth Elements and Yttrium Potentials of Neoproterozoic Peralkaline Siwana Granite of Malani Igneous Suite, Barmer District, Rajasthan. Journal of the Geological Society of India 94, 35–41. https://doi.org/10.1007/s12594-019-1263-0.Bhushan S.K., Somani O.P., 2019. Rare Earth Elements and Yttrium Potentials of Neoproterozoic Peralkaline Siwana Granite of Malani Igneous Suite, Barmer District, Rajasthan. Journal of the Geological Society of India 94, 35–41. https://doi.org/10.1007/s12594-019-1263-0.Drogobuzhskaya S.V., Bayanova T.B., Novikov A.I., Neradovskiy Yu.N., Subbotin V.V., Savchenko E.E., 2019. LA-ICPMS Analysis of Baddeleyite, Zircon, Sulfides from Rocks of the Fennoscandian Shield Complex Deposits in the Arctic Region. Proceedings of the Fersman Scientific Session of the GI KSC RAS. Vol. 16. P. 165–169 (in Russian) [Дрогобужская С.В., Баянова Т.Б., Новиков А.И., Нерадовский Ю.Н., Субботин В.В., Cавченко Е.Э. LA-ICP-MS анализ бадделеита, циркона и сульфидов из пород комплексных месторождений Фенноскандинавского щита в пределах Арктического региона // Труды Ферсмановской научной сессии ГИ КНЦ РАН. 2019. Т. 16. С. 165–169]. https://doi.org/10.31241/fns.2019.16.034.Drogobuzhskaya S.V., Bayanova T.B., Novikov A.I., Neradovskiy Yu.N., Subbotin V.V., Savchenko E.E., 2019. LA-ICPMS Analysis of Baddeleyite, Zircon, Sulfides from Rocks of the Fennoscandian Shield Complex Deposits in the Arctic Region. Proceedings of the Fersman Scientific Session of the GI KSC RAS. Vol. 16. P. 165–169 (in Russian) [Дрогобужская С.В., Баянова Т.Б., Новиков А.И., Нерадовский Ю.Н., Субботин В.В., Cавченко Е.Э. LA-ICP-MS анализ бадделеита, циркона и сульфидов из пород комплексных месторождений Фенноскандинавского щита в пределах Арктического региона // Труды Ферсмановской научной сессии ГИ КНЦ РАН. 2019. Т. 16. С. 165–169]. https://doi.org/10.31241/fns.2019.16.034.Fan H.P., Zhu W.G., Li Z.X., Zhong H., Bai Z.J., He D.F., Chen C.J., Cao C.Y., 2013. Ca. 1.5 Ga Mafic Magmatism in South China during the Break-up of the Supercontinent Nuna/Columbia: The Zhuqing Fe–Ti–V Oxide Ore-Bearing Mafic Intrusions in Western Yangtze Block. Lithos 168–169, 85–98. https://doi.org/10.1016/j.lithos.2013.02.004.Fan H.P., Zhu W.G., Li Z.X., Zhong H., Bai Z.J., He D.F., Chen C.J., Cao C.Y., 2013. Ca. 1.5 Ga Mafic Magmatism in South China during the Break-up of the Supercontinent Nuna/Columbia: The Zhuqing Fe–Ti–V Oxide Ore-Bearing Mafic Intrusions in Western Yangtze Block. Lithos 168–169, 85–98. https://doi.org/10.1016/j.lithos.2013.02.004.Fershtater G.B., 2001. Granitoid Magmatism and Continental Crust Formation (Uralian Orogen). Lithosphere 1, 65–85 (in Russian) [Ферштатер Г.Б. Гранитоидный магматизм и формирование континентальной земной коры в ходе развития уральского орогена // Литосфера. 2001. № 1. С. 62–85].Fershtater G.B., 2001. Granitoid Magmatism and Continental Crust Formation (Uralian Orogen). Lithosphere 1, 65–85 (in Russian) [Ферштатер Г.Б. Гранитоидный магматизм и формирование континентальной земной коры в ходе развития уральского орогена // Литосфера. 2001. № 1. С. 62–85].Fershtater G.B., Bea F., Montero M.P., Scarrow J., 2004. Hornblende Gabbro in the Urals: Types, Geochemistry, and Petrogenesis. Geochemistry International 42 (7), 610–629.Fershtater G.B., Bea F., Montero M.P., Scarrow J., 2004. Hornblende Gabbro in the Urals: Types, Geochemistry, and Petrogenesis. Geochemistry International 42 (7), 610–629.French J.E., Heaman L.M., 2010. Precise U–Pb Dating of Paleoproterozoic Mafic Dyke Swarms of the Dharwar Craton, India: Implications for the Existence of the Neoarchean Supercraton Sclavia. Precambrian Research 183 (3), 416–441. https://doi.org/10.1016/j.precamres.2010.05.003.French J.E., Heaman L.M., 2010. Precise U–Pb Dating of Paleoproterozoic Mafic Dyke Swarms of the Dharwar Craton, India: Implications for the Existence of the Neoarchean Supercraton Sclavia. Precambrian Research 183 (3), 416–441. https://doi.org/10.1016/j.precamres.2010.05.003.Gaft M., Reisfeld R., Panczer G., 2005. Luminescence Spectroscopy of Minerals and Materials. Springer-Verlag, Berlin, Heidelberg, New York, 356 p. https://doi.org/10.1017/S0016756806272972.Gaft M., Reisfeld R., Panczer G., 2005. Luminescence Spectroscopy of Minerals and Materials. Springer-Verlag, Berlin, Heidelberg, New York, 356 p. https://doi.org/10.1017/S0016756806272972.Geisler T., Schaltegger U., Tomaschek F., 2007. Re-Equilibration of Zircon in Aqueous Fluids and Melts. Elements 3 (1), 43–50. https://doi.org/10.2113/gselements.3.1.43.Geisler T., Schaltegger U., Tomaschek F., 2007. Re-Equilibration of Zircon in Aqueous Fluids and Melts. Elements 3 (1), 43–50. https://doi.org/10.2113/gselements.3.1.43.Gorobets B.S., Rogozhin A.A., 2001. Luminescence Spectra of Minerals. Guidebook. VIMS, Moscow, 316 p. (in Russian) [Горобец Б.С., Рогожин А.А. Спектры люминесценции минералов: Справочник. М.: Изд-во ВИМС, 2001. 316 с.].Gorobets B.S., Rogozhin A.A., 2001. Luminescence Spectra of Minerals. Guidebook. VIMS, Moscow, 316 p. (in Russian) [Горобец Б.С., Рогожин А.А. Спектры люминесценции минералов: Справочник. М.: Изд-во ВИМС, 2001. 316 с.].Grimes C.B., John B.E., Kelemen P.B., Mazdab F.K., Wooden J.L., Cheadle M.J., Hanghoj K., Schwartz J.J., 2007. Trace Element Chemistry of Zircons from Oceanic Crust: A Method for Distinguishing Detrital Zircon Provenance. Geology 35 (7), 643–646. https://doi.org/10.1130/g23603a.1.Grimes C.B., John B.E., Kelemen P.B., Mazdab F.K., Wooden J.L., Cheadle M.J., Hanghoj K., Schwartz J.J., 2007. Trace Element Chemistry of Zircons from Oceanic Crust: A Method for Distinguishing Detrital Zircon Provenance. Geology 35 (7), 643–646. https://doi.org/10.1130/g23603a.1.Guo F., Guo J., Wang C.Y., Fan W., Li C., Zhao L., Li H., Li J., 2013. Formation of Mafic Magmas through Lower Crustal AFC Processes – An Example from the Jinan Gabbroic Intrusion in the North China Block. Lithos 179, 157–174. https://doi.org/10.1016/j.lithos.2013.05.018.Guo F., Guo J., Wang C.Y., Fan W., Li C., Zhao L., Li H., Li J., 2013. Formation of Mafic Magmas through Lower Crustal AFC Processes – An Example from the Jinan Gabbroic Intrusion in the North China Block. Lithos 179, 157–174. https://doi.org/10.1016/j.lithos.2013.05.018.Heaman L.M., 2009. The Application of U–Pb Geochronology to Mafic, Ultramafic and Alkaline Rocks: An Evaluation of Three Mineral Standards. Chemical Geology 261 (1–2), 43–52. https://doi.org/10.1016/j.chemgeo.2008.10.021.Heaman L.M., 2009. The Application of U–Pb Geochronology to Mafic, Ultramafic and Alkaline Rocks: An Evaluation of Three Mineral Standards. Chemical Geology 261 (1–2), 43–52. https://doi.org/10.1016/j.chemgeo.2008.10.021.Heaman L.M., LeCheminant A.N., 1993. Paragenesis and U-Pb Systematics of Baddeleyite (ZrO2). Chemical Geology 110 (1–3), 95–126. https://doi.org/10.1016/0009-2541(93)90249-i.Heaman L.M., LeCheminant A.N., 1993. Paragenesis and U-Pb Systematics of Baddeleyite (ZrO2). Chemical Geology 110 (1–3), 95–126. https://doi.org/10.1016/0009-2541(93)90249-i.Ivanyuk G.Yu., Yakovenchuk V.N., Pakhomovsky Y.A., 2002. Kovdor. Laplandia Minerals, Apatity, 326 p. (in Russian) [Иванюк Г.Ю., Яковенчук В.Н., Пахомовский Я.А. Ковдор. Апатиты: Изд-во Минералы Лапландии, 2002. 326 с.].Ivanyuk G.Yu., Yakovenchuk V.N., Pakhomovsky Y.A., 2002. Kovdor. Laplandia Minerals, Apatity, 326 p. (in Russian) [Иванюк Г.Ю., Яковенчук В.Н., Пахомовский Я.А. Ковдор. Апатиты: Изд-во Минералы Лапландии, 2002. 326 с.].Jiang Y., Hsu W., 2012. Petrogenesis of Grove Mountains 020090: An Enriched “Lherzolitic” Shergottite. Meteoritics & Planetary Science 47 (9), 1419–1435. https://doi.org/10.1111/j.1945-5100.2012.01404.x.Jiang Y., Hsu W., 2012. Petrogenesis of Grove Mountains 020090: An Enriched “Lherzolitic” Shergottite. Meteoritics & Planetary Science 47 (9), 1419–1435. https://doi.org/10.1111/j.1945-5100.2012.01404.x.Kallistov G.A., 2014. Duration and Age Stages of the Formation of the Chelyabinsk Granitoid Batholith. In: Informational Collection of Scientific Papers of IGG UB RAS. Yearbook 2013. IGG UB RAS Publishing House, Ekaterinburg, p. 343–349 (in Russian) [Каллистов Г.А. Длительность и возрастные этапы становления Челябинского гранитоидного батолита. Информационный сборник научных трудов ИГГ УрО РАН. Ежегодник-2013. Екатеринбург: Изд-во ИГГ УрО РАН, 2014. C. 343–349].Kallistov G.A., 2014. Duration and Age Stages of the Formation of the Chelyabinsk Granitoid Batholith. In: Informational Collection of Scientific Papers of IGG UB RAS. Yearbook 2013. IGG UB RAS Publishing House, Ekaterinburg, p. 343–349 (in Russian) [Каллистов Г.А. Длительность и возрастные этапы становления Челябинского гранитоидного батолита. Информационный сборник научных трудов ИГГ УрО РАН. Ежегодник-2013. Екатеринбург: Изд-во ИГГ УрО РАН, 2014. C. 343–349].Kallistov G.А., Osipova Т.А., 2017. Geology and Geochemistry of Synplutonic Dykes in the Chelyabinsk Granitoid Massif, South Urals. Geodynamics & Tectonophysics 8 (2), 331–345 (in Russian) [Каллистов Г.А., Осипова Т.А. Геология и геохимия синплутонических даек в Челябинском гранитоидном массиве (Южный Урал) // Геодинамика и тектонофизика. 2017. Т. 8. № 2. С. 331–345]. https://doi.org/10.5800/gt-2017-8-2-0244.Kallistov G.А., Osipova Т.А., 2017. Geology and Geochemistry of Synplutonic Dykes in the Chelyabinsk Granitoid Massif, South Urals. Geodynamics & Tectonophysics 8 (2), 331–345 (in Russian) [Каллистов Г.А., Осипова Т.А. Геология и геохимия синплутонических даек в Челябинском гранитоидном массиве (Южный Урал) // Геодинамика и тектонофизика. 2017. Т. 8. № 2. С. 331–345]. https://doi.org/10.5800/gt-2017-8-2-0244.Klemme S., Meyer H.-P., 2003. Trace Element Partitioning between Baddeleyite and Carbonatite Melt at High Pressures and High Temperatures. Chemical Geology 199 (3–4), 233–242. https://doi.org/10.1016/s0009-2541(03)00081-0.Klemme S., Meyer H.-P., 2003. Trace Element Partitioning between Baddeleyite and Carbonatite Melt at High Pressures and High Temperatures. Chemical Geology 199 (3–4), 233–242. https://doi.org/10.1016/s0009-2541(03)00081-0.Kogarko L.N., Sorokhtina N.V., Kononkova N.N., Klimovich I.V., 2013. Uranium and Thorium in Carbonatitic Minerals from the Guli Massif, Polar Siberia. Geochemistry International 51, 767–776. https://doi.org/10.1134/s0016702913090036.Kogarko L.N., Sorokhtina N.V., Kononkova N.N., Klimovich I.V., 2013. Uranium and Thorium in Carbonatitic Minerals from the Guli Massif, Polar Siberia. Geochemistry International 51, 767–776. https://doi.org/10.1134/s0016702913090036.Li L., Shi Y., Anderson J.L., Cui M., 2016. Sensitive High-Resolution Ion Microprobe U-Pb Dating of Baddeleyite and Zircon from a Monzonite Porphyry in the Xiaoshan Area, Western Henan Province, China: Constraints on Baddeleyite and Zircon Formation Process. Geosphere 12 (4), 1362–1377. https://doi.org/10.1130/ges01328.1.Li L., Shi Y., Anderson J.L., Cui M., 2016. Sensitive High-Resolution Ion Microprobe U-Pb Dating of Baddeleyite and Zircon from a Monzonite Porphyry in the Xiaoshan Area, Western Henan Province, China: Constraints on Baddeleyite and Zircon Formation Process. Geosphere 12 (4), 1362–1377. https://doi.org/10.1130/ges01328.1.Ludwig K.R., 1999. User’s Manual for ISOPLOT/EX, Version 2. A Geochronological Toolkit for Microsoft Excel. Berkeley Geochronology Center Special Publication 1a, 120 p.Ludwig K.R., 1999. User’s Manual for ISOPLOT/EX, Version 2. A Geochronological Toolkit for Microsoft Excel. Berkeley Geochronology Center Special Publication 1a, 120 p.Lumpkin G.R., 1999. Physical and Chemical Characteristics of Baddeleyite (Monoclinic Zirconia) in Natural Environments: An Overview and Case Study. Journal of Nuclear Materials 274 (1–2), 206–217. https://doi.org/10.1016/s0022-3115(99)00066-5.Lumpkin G.R., 1999. Physical and Chemical Characteristics of Baddeleyite (Monoclinic Zirconia) in Natural Environments: An Overview and Case Study. Journal of Nuclear Materials 274 (1–2), 206–217. https://doi.org/10.1016/s0022-3115(99)00066-5.Mackie R.A., Scoates J.S., Weis D., 2009. Age and Nd–Hf Isotopic Constraints on the Origin of Marginal Rocks from the Muskox Layered Intrusion (Nunavut, Canada) and Implications for the Evolution of the 1.27Ga Mackenzie Large Igneous Province. Precambrian Research 172 (1–2), 46–66. https://doi.org/10.1016/j.precamres.2009.03.007.Mackie R.A., Scoates J.S., Weis D., 2009. Age and Nd–Hf Isotopic Constraints on the Origin of Marginal Rocks from the Muskox Layered Intrusion (Nunavut, Canada) and Implications for the Evolution of the 1.27Ga Mackenzie Large Igneous Province. Precambrian Research 172 (1–2), 46–66. https://doi.org/10.1016/j.precamres.2009.03.007.Malitch K.N., Belousova E.A., Griffin W.L., Badanina I.Yu., Knauf V.V., O’Reilly S.Y., Pearson N.J., 2017. Laurite and Zircon from the Finero Chromitites (Italy): New Insights into Evolution of the Subcontinental Mantle. Ore Geology Reviews 90, 210–225. http://dx.doi.org/10.1016/j.oregeorev.2017.06.027.Malitch K.N., Belousova E.A., Griffin W.L., Badanina I.Yu., Knauf V.V., O’Reilly S.Y., Pearson N.J., 2017. Laurite and Zircon from the Finero Chromitites (Italy): New Insights into Evolution of the Subcontinental Mantle. Ore Geology Reviews 90, 210–225. http://dx.doi.org/10.1016/j.oregeorev.2017.06.027.Malitch K.N., Khiller V.V., Badanina I.Y., Belousova E.A., 2015. Results of Dating of Thorianite and Baddeleyite from Carbonatites of the Guli Massif, Russia. Doklady Earth Sciences 464, 1029–1032. https://doi.org/10.1134/S1028334X15100050.Malitch K.N., Khiller V.V., Badanina I.Y., Belousova E.A., 2015. Results of Dating of Thorianite and Baddeleyite from Carbonatites of the Guli Massif, Russia. Doklady Earth Sciences 464, 1029–1032. https://doi.org/10.1134/S1028334X15100050.Martin H., Smithies R.H., Rapp R., Moyen J.-F., Champion D., 2005. An Overview of Adakite, Tonalite-Trondhjemite-Granodiorite (TTG), and Sanukitoid: Relationships and Some Implications for Crustal Evolution. Lithos 79 (1–2), 1–24. https://doi.org/10.1016/j.lithos.2004.04.048.Martin H., Smithies R.H., Rapp R., Moyen J.-F., Champion D., 2005. An Overview of Adakite, Tonalite-Trondhjemite-Granodiorite (TTG), and Sanukitoid: Relationships and Some Implications for Crustal Evolution. Lithos 79 (1–2), 1–24. https://doi.org/10.1016/j.lithos.2004.04.048.Meng F., Zhang J., 2009. Genesis of the Mega-crystal Zircons in the Dunite Veins of North Qaidam Mountains, Northwestern China. Chinese Science Bulletin 54, 4688–4696. https://doi.org/10.1007/s11434-009-0205-4.Meng F., Zhang J., 2009. Genesis of the Mega-crystal Zircons in the Dunite Veins of North Qaidam Mountains, Northwestern China. Chinese Science Bulletin 54, 4688–4696. https://doi.org/10.1007/s11434-009-0205-4.Montel J.M., Foret S., Veschambre M., Nicollet C., Provost A., 1996. Electron Microprobe Dating of Monazite. Chemical Geology 131 (1–4), 37–53. https://doi.org/10.1016/0009-2541(96)00024-1.Montel J.M., Foret S., Veschambre M., Nicollet C., Provost A., 1996. Electron Microprobe Dating of Monazite. Chemical Geology 131 (1–4), 37–53. https://doi.org/10.1016/0009-2541(96)00024-1.Nedosekova I.L., 2012. Age and Sources of the Material in the Ilmen-Vishnevogorsk Alkaline Complex (Ural, Russia): Geochemical and Isotopic Rb-Sr, Sm-Nd, U-Pb and Lu-Hf Data. Lithosphere 5, 77–95 (in Russian) [Недосекова И.Л. Возраст и источники вещества Ильмено-Вишневогорского щелочного комплекса (Урал, Россия): геохимические и изотопные Rb-Sr, Sm-Nd, U-Pb и Lu-Hf данные // Литосфера. 2012. № 5. С. 77–95].Nedosekova I.L., 2012. Age and Sources of the Material in the Ilmen-Vishnevogorsk Alkaline Complex (Ural, Russia): Geochemical and Isotopic Rb-Sr, Sm-Nd, U-Pb and Lu-Hf Data. Lithosphere 5, 77–95 (in Russian) [Недосекова И.Л. Возраст и источники вещества Ильмено-Вишневогорского щелочного комплекса (Урал, Россия): геохимические и изотопные Rb-Sr, Sm-Nd, U-Pb и Lu-Hf данные // Литосфера. 2012. № 5. С. 77–95].Nedosekova I.L., Belousova E.A., Belyatsky B.V., 2014. The U-Pb Age and Lu-Hf Isotope Systems of Zircons in the Ilmen-Vishnevogorsk Alkaline-Carbonatite Complex, South Urals. Lithosphere 5, 19–32 (in Russian) [Недосекова И.Л., Белоусова Е.А., Беляцкий Б.В. U-Pb-возраст и Lu-Hf изотопные системы цирконов Ильмено-Вишневогорского щелочно-карбонатитового комплекса, Южный Урал // Литосфера. 2014. № 5. С. 19–32].Nedosekova I.L., Belousova E.A., Belyatsky B.V., 2014. The U-Pb Age and Lu-Hf Isotope Systems of Zircons in the Ilmen-Vishnevogorsk Alkaline-Carbonatite Complex, South Urals. Lithosphere 5, 19–32 (in Russian) [Недосекова И.Л., Белоусова Е.А., Беляцкий Б.В. U-Pb-возраст и Lu-Hf изотопные системы цирконов Ильмено-Вишневогорского щелочно-карбонатитового комплекса, Южный Урал // Литосфера. 2014. № 5. С. 19–32].Osipova Т.А., Kallistov G.A., Zaitseva M.V., 2019. Zircon in High-Mg Diorite of the Chelyabinsk Massif (South Urals): Morphology, Geochemical Signature, and Petrogenesis Implications. Geodynamics & Tectonophysics 10 (2), 289–308 (in Russian) [Осипова Т.А., Каллистов Г.А., Зайцева М.В. Циркон из высокомагнезиального диорита Челябинского массива (Южный Урал): морфология, геохимические особенности, петрогенетические аспекты // Геодинамика и тектонофизика. 2017. Т. 10. № 2. С. 289–308]. https://doi.org/10.5800/gt-2019-10-2-0415.Osipova Т.А., Kallistov G.A., Zaitseva M.V., 2019. Zircon in High-Mg Diorite of the Chelyabinsk Massif (South Urals): Morphology, Geochemical Signature, and Petrogenesis Implications. Geodynamics & Tectonophysics 10 (2), 289–308 (in Russian) [Осипова Т.А., Каллистов Г.А., Зайцева М.В. Циркон из высокомагнезиального диорита Челябинского массива (Южный Урал): морфология, геохимические особенности, петрогенетические аспекты // Геодинамика и тектонофизика. 2017. Т. 10. № 2. С. 289–308]. https://doi.org/10.5800/gt-2019-10-2-0415.Pavlov N.V., 1949. Chemical Composition of Cr-Spinels in Relation to the Petrographic Rock Composition of Ultrabasic Intrusions. Proceedings of the Institute of Geological Sciences of the USSR Academy of Sciences. Ore Deposits Series 103 (13). Nauka, Moscow, 88 p. (in Russian) [Павлов Н.В. Химический состав хромшпинелидов в связи с петрографическим составом пород ультраосновных интрузивов // Труды ИГН АН СССР. Серия рудных месторождений 1949. Вып. 103. № 13. М.: Наука, 1949. 88 с.].Pavlov N.V., 1949. Chemical Composition of Cr-Spinels in Relation to the Petrographic Rock Composition of Ultrabasic Intrusions. Proceedings of the Institute of Geological Sciences of the USSR Academy of Sciences. Ore Deposits Series 103 (13). Nauka, Moscow, 88 p. (in Russian) [Павлов Н.В. Химический состав хромшпинелидов в связи с петрографическим составом пород ультраосновных интрузивов // Труды ИГН АН СССР. Серия рудных месторождений 1949. Вып. 103. № 13. М.: Наука, 1949. 88 с.].Popova V.I., Gubin V.A., Churin E.I., Kotlyarov V.A., Khiller V.V., 2013. Rare Metal Mineralization in Granite Pegmatites of Rezhevsky Area at the Middle Urals. Proceedings of the Russian Mineralogical Society 142 (1), 23–38 (in Russian) [Попова В.И., Губин В.А., Чурин Е.И., Котляров В.А., Хиллер В.В. Редкометалльная минерализация гранитных пегматитов Режевского района на Среднем Урале // Записки Российского минералогического общества. 2013. Т. 142. № 1. C. 23–38].Popova V.I., Gubin V.A., Churin E.I., Kotlyarov V.A., Khiller V.V., 2013. Rare Metal Mineralization in Granite Pegmatites of Rezhevsky Area at the Middle Urals. Proceedings of the Russian Mineralogical Society 142 (1), 23–38 (in Russian) [Попова В.И., Губин В.А., Чурин Е.И., Котляров В.А., Хиллер В.В. Редкометалльная минерализация гранитных пегматитов Режевского района на Среднем Урале // Записки Российского минералогического общества. 2013. Т. 142. № 1. C. 23–38].Pouchou J.L., Pichoir F., 1984. A New Model for Quantitative X-Ray Micro-Analysis. Part I: Application to the Analysis of Homogeneous Samples. La Recherche Aerospatiale 3, 13–38.Pouchou J.L., Pichoir F., 1984. A New Model for Quantitative X-Ray Micro-Analysis. Part I: Application to the Analysis of Homogeneous Samples. La Recherche Aerospatiale 3, 13–38.Pribavkin S.V., Kallistov G.A., Оsipova Т.A., Gottman I.A., Zin’kova E.A., 2019. Geochemical Behavior of Chromium in Minerals of High-Mg Rocks, Associated with Granitoid Massifs of the Urals. Lithosphere 19 (3), 416–435 (in Russian) [Прибавкин С.В., Каллистов Г.А., Осипова Т.А., Готтман И.А., Зинькова Е.А. Распределение хрома в минералах высокомагнезиальных пород, ассоциированных с гранитоидными массивами Урала // Литосфера. 2019. Т. 19. № 3. С. 416–435]. https://doi.org/10.24930/1681-9004-2019-19-3-416-435.Pribavkin S.V., Kallistov G.A., Оsipova Т.A., Gottman I.A., Zin’kova E.A., 2019. Geochemical Behavior of Chromium in Minerals of High-Mg Rocks, Associated with Granitoid Massifs of the Urals. Lithosphere 19 (3), 416–435 (in Russian) [Прибавкин С.В., Каллистов Г.А., Осипова Т.А., Готтман И.А., Зинькова Е.А. Распределение хрома в минералах высокомагнезиальных пород, ассоциированных с гранитоидными массивами Урала // Литосфера. 2019. Т. 19. № 3. С. 416–435]. https://doi.org/10.24930/1681-9004-2019-19-3-416-435.Pribavkin S.V., Ronkin Y.L., Travin A.V., Ponomarchuk V.A., 2007. New Data on the Age of Lamproite-Lamprophyre Magmatism in the Urals. Doklady Earth Sciences 413, 213–215. https://doi.org/10.1134/s1028334x07020171.Pribavkin S.V., Ronkin Y.L., Travin A.V., Ponomarchuk V.A., 2007. New Data on the Age of Lamproite-Lamprophyre Magmatism in the Urals. Doklady Earth Sciences 413, 213–215. https://doi.org/10.1134/s1028334x07020171.Puchkov V.N., 2010. Geology of the Urals and the Surroundings: Topical Problems of Stratigraphy, Tectonics, Geodynamics and Metallogeny. DizajnPoligrafServis, Ufa, 280 p. (in Russian) [Пучков В.Н. Геология Урала и Приуралья (актуальные вопросы стратиграфии, тектоники, геодинамики и металлогении). Уфа: ДизайнПолиграфСервис, 2010. 280 с.].Puchkov V.N., 2010. Geology of the Urals and the Surroundings: Topical Problems of Stratigraphy, Tectonics, Geodynamics and Metallogeny. DizajnPoligrafServis, Ufa, 280 p. (in Russian) [Пучков В.Н. Геология Урала и Приуралья (актуальные вопросы стратиграфии, тектоники, геодинамики и металлогении). Уфа: ДизайнПолиграфСервис, 2010. 280 с.].Qian Q., Hermann J., 2010. Formation of High-Mg Diorites through Assimilation of Peridotite by Monzodiorite Magma at Crustal Depths. Journal of Petrology 57 (7), 1381–1416. https://doi.org/10.1093/petrology/egq023.Qian Q., Hermann J., 2010. Formation of High-Mg Diorites through Assimilation of Peridotite by Monzodiorite Magma at Crustal Depths. Journal of Petrology 57 (7), 1381–1416. https://doi.org/10.1093/petrology/egq023.Rajesh V.J., Arai S., 2006. Baddeleyite-Apatite-Spinel-Phlogopite (BASP) Rock in Achankovil Shear Zone, South India, as a Probable Cumulate from Melts of Carbonatite Affinity. Lithos 90 (1–2), 1–18. https://doi.org/10.1016/j.lithos.2006.01.004.Rajesh V.J., Arai S., 2006. Baddeleyite-Apatite-Spinel-Phlogopite (BASP) Rock in Achankovil Shear Zone, South India, as a Probable Cumulate from Melts of Carbonatite Affinity. Lithos 90 (1–2), 1–18. https://doi.org/10.1016/j.lithos.2006.01.004.Rajesh V.J., Yokoyama K., Santosh M., Arai S., Oh C.W., Kim S.W., 2006. Zirconolite and Baddeleyite in an Ultramafic Suite from Southern India: Early Ordovician Carbonatite‐Type Melts Associated with Extensional Collapse of the Gondwana Crust. The Journal of Geology 114 (2), 171–188. https://doi.org/10.1086/499571.Rajesh V.J., Yokoyama K., Santosh M., Arai S., Oh C.W., Kim S.W., 2006. Zirconolite and Baddeleyite in an Ultramafic Suite from Southern India: Early Ordovician Carbonatite‐Type Melts Associated with Extensional Collapse of the Gondwana Crust. The Journal of Geology 114 (2), 171–188. https://doi.org/10.1086/499571.Robinson S.C., Sabina A.P., 1955. Uraninite and Thorianite from Ontario and Quebec1. American Mineralogist 40 (7–8), 624–633.Robinson S.C., Sabina A.P., 1955. Uraninite and Thorianite from Ontario and Quebec1. American Mineralogist 40 (7–8), 624–633.Ronkin Yu.L., Efimov A.A., Lepikhina G.A., Maslov A.V., Rodionov N.V., 2013. U-Pb Dating of the Baddeleytte-Zircon System from PT-Bearing Dunite of the Konder Massif, Aldan Shield: New Data. Doklady Earth Sciences 450, 607–612. https://doi.org/10.1134/s1028334x13060135.Ronkin Yu.L., Efimov A.A., Lepikhina G.A., Maslov A.V., Rodionov N.V., 2013. U-Pb Dating of the Baddeleytte-Zircon System from PT-Bearing Dunite of the Konder Massif, Aldan Shield: New Data. Doklady Earth Sciences 450, 607–612. https://doi.org/10.1134/s1028334x13060135.Scharer U., Berndt J., Deutsch A., 2011. The Genesis of Deep-Mantle Xenocrystic Zircon and Baddeleyite Megacrysts (Mbuji-Mayi Kimberlite): Trace-Element Patterns. European Journal of Mineralogy 23 (2), 241–255. https://doi.org/10.1127/0935-1221/2011/0023-2088.Scharer U., Berndt J., Deutsch A., 2011. The Genesis of Deep-Mantle Xenocrystic Zircon and Baddeleyite Megacrysts (Mbuji-Mayi Kimberlite): Trace-Element Patterns. European Journal of Mineralogy 23 (2), 241–255. https://doi.org/10.1127/0935-1221/2011/0023-2088.Standards for Electron Probe Microanalysis, 2020. Available from: https://www.pandhdevelopments.com (Last Accessed July 2020).Standards for Electron Probe Microanalysis, 2020. Available from: https://www.pandhdevelopments.com (Last Accessed July 2020).Sun J., Tappe S., Kostrovitsky S.I., Liu C.-Z., Skuzovatov S.Yu., Wu F.-Y., 2018. Mantle Sources of Kimberlites through Time: A U-Pb and Lu-Hf Isotope Study of Zircon Megacrysts from the Siberian Diamond Fields. Chemical Geology 479, 228–240. https://doi.org/10.1016/j.chemgeo.2018.01.013.Sun J., Tappe S., Kostrovitsky S.I., Liu C.-Z., Skuzovatov S.Yu., Wu F.-Y., 2018. Mantle Sources of Kimberlites through Time: A U-Pb and Lu-Hf Isotope Study of Zircon Megacrysts from the Siberian Diamond Fields. Chemical Geology 479, 228–240. https://doi.org/10.1016/j.chemgeo.2018.01.013.Tatsumi Y., 2008. Making Continental Crust: The Sanukitoid Connection. Chinese Science Bulletin 53, 1620–1633. https://doi.org/10.1007/s11434-008-0185-9.Tatsumi Y., 2008. Making Continental Crust: The Sanukitoid Connection. Chinese Science Bulletin 53, 1620–1633. https://doi.org/10.1007/s11434-008-0185-9.Votyakov S.L., Shchapova Yu.V., Hiller V.V., 2011. Crystal Chemistry and Physics of Radiation–Thermal Effects in U-Th-Containing Minerals as a Basis for Their Chemical Microprobe Dating. IGG UB RAS Publishing House, Еkaterinburg, 340 p. (in Russian) [Вотяков С.Л., Щапова Ю.В., Хиллер В.В. Кристаллохимия и физика радиационно-термических эффектов в ряде U-Th-содержащих минералов как основа для их химического микрозондового датирования. Екатеринбург: Изд-во ИГГ УрО РАН, 2011. 340 с.].Votyakov S.L., Shchapova Yu.V., Hiller V.V., 2011. Crystal Chemistry and Physics of Radiation–Thermal Effects in U-Th-Containing Minerals as a Basis for Their Chemical Microprobe Dating. IGG UB RAS Publishing House, Еkaterinburg, 340 p. (in Russian) [Вотяков С.Л., Щапова Ю.В., Хиллер В.В. Кристаллохимия и физика радиационно-термических эффектов в ряде U-Th-содержащих минералов как основа для их химического микрозондового датирования. Екатеринбург: Изд-во ИГГ УрО РАН, 2011. 340 с.].Wall C.J., Scoates J.S., Weis D., Friedman R.M., Amini M., Meurer W.R., 2018. The Stillwater Complex: Integrating Zircon Geochronological and Geochemical Constraints on the Age, Emplacement History and Crystallization of a Large, Open-System Layered Intrusion. Journal of Petrology 59 (1), 153–190. https://doi.org/10.1093/petrology/egy024.Wall C.J., Scoates J.S., Weis D., Friedman R.M., Amini M., Meurer W.R., 2018. The Stillwater Complex: Integrating Zircon Geochronological and Geochemical Constraints on the Age, Emplacement History and Crystallization of a Large, Open-System Layered Intrusion. Journal of Petrology 59 (1), 153–190. https://doi.org/10.1093/petrology/egy024.Wingate M.T.D., Campbell I.H., Harris L.B., 2000. SHRIMP Baddeleyite Age for the Fraser Dyke Swarm, Southeast Yilgarn Craton, Western Australia. Australian Journal of Earth Sciences 47 (2), 309–313. https://doi.org/10.1046/j.1440-0952.2000.00783.x.Wingate M.T.D., Campbell I.H., Harris L.B., 2000. SHRIMP Baddeleyite Age for the Fraser Dyke Swarm, Southeast Yilgarn Craton, Western Australia. Australian Journal of Earth Sciences 47 (2), 309–313. https://doi.org/10.1046/j.1440-0952.2000.00783.x.Yurichev A.N., Chernyshov A.I., Kul’kov A.S., 2016. New Ore Minerals of the Kingash Ultramafic Massif (Northwestern Areas of Eastern Sayan). Proceedings of the Russian Mineralogical Society 145 (3), 14–22 (in Russian) [Юричев А.Н., Чернышов А.И., Кульков А.С. Новые рудные минералы Кингашского ультрамафитового массива (северо-запад Восточного Саяна) // Записки Российского минералогического общества. 2016. Т. 145. № 3. C. 14–22].Yurichev A.N., Chernyshov A.I., Kul’kov A.S., 2016. New Ore Minerals of the Kingash Ultramafic Massif (Northwestern Areas of Eastern Sayan). Proceedings of the Russian Mineralogical Society 145 (3), 14–22 (in Russian) [Юричев А.Н., Чернышов А.И., Кульков А.С. Новые рудные минералы Кингашского ультрамафитового массива (северо-запад Восточного Саяна) // Записки Российского минералогического общества. 2016. Т. 145. № 3. C. 14–22].Zaccarini F., Stumpfl E.F., Garuti G., 2004. Zirconolite and Zr–Th–U Minerals in Chromitites of the Finero Complex, Western Alps, Italy: Evidence for Carbonatite-Type Metasomatism in a Subcontinental Mantle Plume. Mineralogical Association of Canada 42 (6), 1825. https://doi.org/10.2113/gscanmin.42.6.1825.Zaccarini F., Stumpfl E.F., Garuti G., 2004. Zirconolite and Zr–Th–U Minerals in Chromitites of the Finero Complex, Western Alps, Italy: Evidence for Carbonatite-Type Metasomatism in a Subcontinental Mantle Plume. Mineralogical Association of Canada 42 (6), 1825. https://doi.org/10.2113/gscanmin.42.6.1825.Zamyatin D.A., Shchapova Yu.V., Votyakov S.L., Nasdala L., Lenz C., 2017. Alteration and Chemical U-Th-Total Pb Dating of Heterogeneous High-Uranium Zircon from a Pegmatite from the Aduiskii Massif, Middle Urals, Russia. Mineralogy and Petrology 111, 475–497. https://doi.org/10.1007/s00710-017-0513-3.Zamyatin D.A., Shchapova Yu.V., Votyakov S.L., Nasdala L., Lenz C., 2017. Alteration and Chemical U-Th-Total Pb Dating of Heterogeneous High-Uranium Zircon from a Pegmatite from the Aduiskii Massif, Middle Urals, Russia. Mineralogy and Petrology 111, 475–497. https://doi.org/10.1007/s00710-017-0513-3.Zamyatin D.A., Votyakov S.L., Shchapova Yu.V., 2020. Cathodoluminescence Spectrometry of Zircon: To the Analysis Technique Using a Jeol JSM 6390 LV SEM with a Horiba H-CLUE iHR500 Unit. In: Minerals: Structure, Properties, and Research Methods. Proceedings of Materials of the XI All-Russia Youth Scientific Conference (May 25–28, 2020). IGG UB RAS Publishing House, Ekaterinburg, p. 96–99 (in Russian) [Замятин Д.А., Вотяков С.Л., Щапова Ю.В. Катодолюминесцентная спектрометрия циркона: к методике анализа на СЭМ Jeol JSM6390LV c приставкой Horiba H-CLUE iHR500 // Минералы: строение, свойства, методы исследования: Материалы XI Всероссийской молодежной научной конференции (25–28 мая 2020 г.). Екатеринбург: Изд-во ИГГ УрО РАН, 2020. С. 96–99].Zamyatin D.A., Votyakov S.L., Shchapova Yu.V., 2020. Cathodoluminescence Spectrometry of Zircon: To the Analysis Technique Using a Jeol JSM 6390 LV SEM with a Horiba H-CLUE iHR500 Unit. In: Minerals: Structure, Properties, and Research Methods. Proceedings of Materials of the XI All-Russia Youth Scientific Conference (May 25–28, 2020). IGG UB RAS Publishing House, Ekaterinburg, p. 96–99 (in Russian) [Замятин Д.А., Вотяков С.Л., Щапова Ю.В. Катодолюминесцентная спектрометрия циркона: к методике анализа на СЭМ Jeol JSM6390LV c приставкой Horiba H-CLUE iHR500 // Минералы: строение, свойства, методы исследования: Материалы XI Всероссийской молодежной научной конференции (25–28 мая 2020 г.). Екатеринбург: Изд-во ИГГ УрО РАН, 2020. С. 96–99].Zhu Y.-S., Yang J.-H., Wang H., Wu F.-Y., 2020. Mesoproterozoic (~1.32 Ga) Modification of Lithospheric Mantle beneath the North China Craton Caused by Break-up of the Columbia Supercontinent. Precambrian Research 342, 105674. https://doi.org/10.1016/j.precamres.2020.105674.Zhu Y.-S., Yang J.-H., Wang H., Wu F.-Y., 2020. Mesoproterozoic (~1.32 Ga) Modification of Lithospheric Mantle beneath the North China Craton Caused by Break-up of the Columbia Supercontinent. Precambrian Research 342, 105674. https://doi.org/10.1016/j.precamres.2020.105674.

The authors declare that there are no conflicts of interest present.